The Preparative Chemistry of Cobalt (III) Complexes Starting from Tricarbonatocobaltate (III)
نویسندگان
چکیده
منابع مشابه
PREPARATION AND CHARACTERIZATION OF Mn (III) COMPLEXES
We have prepared and characterized a few Mn (III) complexes by using a few bidentate and tridentate ligands. Spectra of the manganese (III) ion in a variety of molecular environments are reported. On the basis of solution spectra, some of these complexes seem to be typically distorted
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In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co-N bond lengths lie in the range 1.960 (5)-1.997 (5) Å. In the anion, the In(III) atom is coordin-ated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted octa-hedral geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds form an extensive hydrogen-...
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ژورنال
عنوان ژورنال: Proceedings of the Japan Academy
سال: 1974
ISSN: 0021-4280
DOI: 10.2183/pjab1945.50.779